钯催化剂:
编号 | 中文名 | 简写 | 结构式 | 分子量 | CAS | 备库数量 | 备注 |
1 | 醋酸钯 | Pd(OAc)2 | 224.5 | 3375-31-3 | 100 g | ||
2 | 氯化钯 | PdCl2 | 177 | 7647-10-1 | 100 g | ||
3 | 四三苯基磷钯 | Pd(PPh3)4 | 1155.6 | 14221-01-3 | 25 g | 易变质 | |
4 | [1,1'-双(二苯基磷)二茂铁]二氯化钯 | Pd(dppf)Cl2 |
| 731.71 | 72287-26-4 | 100g | 经常以氯仿或二氯络活物存在 |
5 | 双三苯基磷二氯化钯 | Pd(PPh3)2Cl2 |
| 701.9 | 13965-03-2 | 100 g | |
6 | 三（二亚苄基丙酮）二钯 | pd2(dba)3 |
| 915.7 | 51364-51-3 | 100 g | Buchwald-Hartwig最常用催化剂 |
7 | 烯丙基氯化钯(II)二聚体 | [PdCl（ally）2] |
| 363.8 | 12012-95-2 | 10 g | |
8 | [1,1'-双(二苯基膦基)二茂铁]二氯化钯 | Pd(dppp)Cl2 |
| 731.7 | 72287-26-4 | 25g | |
9 | 乙酰丙酮钯 | Pd(acac)2 | 304.6 | 14024-61-4 | 10 g | 聚合反应应用较多 | |
配体:
中文名 | 简写 | 结构式 | 分子量 | CAS | 备库数量 | 备注 | |
1 | 三苯基膦 | PPh3 | 262.30 | 603-35-0 | 250g | ||
2 | 2-双环己基膦-2',4',6'-三异丙基联苯 | XPhos |
| 476.7 | 564483-18-7 | 25 g | Buchwald-Hartwig最常用配体 |
3 | 2-双环己基膦-2',6'-二甲氧基联苯 | SPhos |
| 410.53 | 657408-07-6 | 25g | |
4 | 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯 | RuPhos |
| 466.4 | 787618-22-8 | 25g | |
5 | 4,5-双二苯基膦-9,9-二甲基氧杂蒽 | XantPhos |
| 578.62 | 161265-03-8 | 25g | |
6 | 1,1'-双(二苯基膦)二茂铁 | Dppf |
| 554.4 | 12150-46-8 | 100g | |
7 | 1,1'-联二萘酚 | BINOL |
| 286 | 18531-99-2 | 100g | |
8 | (±)-2,2'-双-(二苯膦基)-1,1'-联萘, | BINAP |
| 622.6 | 98327-87-8 | 100g | |
9 | 三环己基膦 | Pcy3 | 280.4 | 2622-14-2 | 100g | 怕氧化 | |
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