《有机化学》第三学期模拟试题（1）
题号 | 一 | 二 | 三 | 四 | 五 | 六 | 七 | 总分 |
分值 | 8 | 15 | 21 | 12 | 25 | 10 | 9 | 100 |
得分 | ||||||||
一、用系统命名法命名下列化合物或写出相应的结构式(8分)
（共8题，每题1分）
1.苦味酸 2.（１S,3R）-3-溴环己醇
![](https://wkrtcs.bdimg.com/rtcs/image?w=442&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"442","h":"223","dataType":"gif","c":"word/media/image1.png"})
7. n-Bu- 8. NBS
二、选择一个正确的答案，填写在括号内。（15分）(共5题，每题3分)
1. 苯环上最易发生卤代反应的是（ ）
![](https://wkrtcs.bdimg.com/rtcs/image?w=435&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"435","h":"95","dataType":"gif","c":"word/media/image2.png"})
2. 在水中溶解度最大的化合物为（ ）
![](https://wkrtcs.bdimg.com/rtcs/image?w=487&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"487","h":"59","dataType":"gif","c":"word/media/image3.png"})
3. 能与三氯化铁溶液发生显色反应的是（ ）
![](https://wkrtcs.bdimg.com/rtcs/image?w=431&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"431","h":"111","dataType":"gif","c":"word/media/image4.png"})
4. 下列碳正离子的稳定性次序为（ ）：
![](https://wkrtcs.bdimg.com/rtcs/image?w=464&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"464","h":"45","dataType":"gif","c":"word/media/image5.png"})
A. ④>①>②>③ B.①>②>③>④
C. ③>②>①>④ D.②>③>①>④
5.下列化合物中酸性最强的是( )
![](https://wkrtcs.bdimg.com/rtcs/image?w=439&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"439","h":"97","dataType":"gif","c":"word/media/image6.png"})
三、完成下列反应式或填写反应条件 （21分）（共14空格，每空格1.5分）
![](https://wkrtcs.bdimg.com/rtcs/image?w=498&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"498","h":"45","dataType":"gif","c":"word/media/image7.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=385&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"385","h":"91","dataType":"gif","c":"word/media/image8.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=415&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"415","h":"49","dataType":"gif","c":"word/media/image9.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=360&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"360","h":"47","dataType":"gif","c":"word/media/image10.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=480&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"480","h":"155","dataType":"gif","c":"word/media/image11.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=542&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"542","h":"43","dataType":"gif","c":"word/media/image12.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=379&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"379","h":"112","dataType":"gif","c":"word/media/image13.png"})
四、回答下列问题 （12分)(共3题，每题4分）
1、比较下列化合物亲电反应的速度，请解释原因。
苯酚、硝基苯、苯甲酸、苯、甲苯
2、下列化合物进行碱性水解时的活性顺序：
苄氯，对硝基苄氯，间硝基苄氯，对甲基苄氯，对甲氧基苄氯。
3、卤烷与氢氧化钠在水与乙醇混合物中进行反旅游区，指出哪些属于SN2历程，哪些属于SN1历程。
⑴产物的构型完全转化 ⑵反应不分阶段，一步完成
⑶增加溶剂的含水量反应速度明显加快 ⑷叔卤烷速度大于仲卤烷
五、合成（少于三个碳原子的烃类化合物、苯、无机原料任选 ）
（25分）(共5题，每题5分)
![](https://wkrtcs.bdimg.com/rtcs/image?w=94.666666666667&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"94.666666666667","h":"68","dataType":"gif","c":"word/media/image14.png"})
1． 2.
![](https://wkrtcs.bdimg.com/rtcs/image?w=186.66666666667&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"186.66666666667","h":"62.666666666667","dataType":"gif","c":"word/media/image15.png"})
![](https://wkrtcs.bdimg.com/rtcs/image?w=173.33333333333&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"173.33333333333","h":"42.666666666667","dataType":"gif","c":"word/media/image16.png"})
3. 苯乙醇 4.
5. 2,6-二硝基苯酚
六、推测结构。（10分）(共2题，每题5分)
1、有机物A和B分子式都为C6H12，二者在室温下均能使Br2-CCl4褪色，但不能被KMnO4氧化，二者氢化产物都是3-甲基戊烷。但A与HI反应主要得到3-甲基-3-碘戊烷， 而B则得到3-甲基-2-碘戊烷。 试推导A和B的构造式。
2、分子式为C3H8O的有机物， 其红外光谱中3600-3100区间有一强而宽的吸收带，其HNMR谱中δ=1.2 双峰（6H）；δ=3.9 多峰（1H）； δ=4.9 单峰（1H）。 试推导该有机物的结构式。
七、鉴别下列各组化合物及分离提纯。（9分)(共3题，每题3分）
1. 1-丁炔 2-丁炔 1，3-丁二烯 丁烷
![](https://wkrtcs.bdimg.com/rtcs/image?w=368&md5sum=ba7ed35bbf507ae9b4fd13f438a7011a&sign=5cd9d8fd51&rtcs_flag=1&rtcs_ver=3.1&l=webapp&bucketNum=24&ipr={"t":"img","w":"368","h":"119","dataType":"gif","c":"word/media/image17.png"})
3. 提纯：乙烯中含有少量乙炔
本文来源：https://www.2haoxitong.net/k/doc/c18dc0f17c1cfad6195fa768.html
文档为doc格式