![](https://wkrtcs.bdimg.com/rtcs/image?w=553&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"553","h":"334","dataType":"png","c":"word/media/image1_1.png","imgOriW":568,"imgOriH":343})
简介：分子式(u-SCH2CH2CH2S)Fe(CO)3Fe(CO)2[P(CH2OH)3]，结晶为层状，两层分子的P(CH2OH)3基团通过氢键形成二维网络。偶然发现二维氢键网络中的羟基氧原子从某个角度看恰好呈波浪状分布，遂画此图。其中多面体为Fe2及其周围的配位原子，悬挂于波浪状网络的波峰和波谷。
![](https://wkrtcs.bdimg.com/rtcs/image?w=486&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"486","h":"521","dataType":"png","c":"word/media/image2_1.png","imgOriW":1337,"imgOriH":1433})
这是首例在离子液体中的得到含有硫属阳离子族的化合物。该化合物含有[Sb7S8Br2]3+阳离子族和[AlCl4]1-阴离子，[Sb7S8Br2]3+阳离子族由两个[Sb4S4Br]3+类立方烷通过公用一个Sb顶点组成。[Sb7S8Br2]3+阳离子族沿a方向排列，形成的空隙被[AlCl4]1-四面体阴离子占据。
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![](https://wkrtcs.bdimg.com/rtcs/image?w=547&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"547","h":"487","dataType":"jpeg","c":"word/media/image3.jpeg","imgOriW":897,"imgOriH":798})
Angew. Chem. Int. Ed. 2004, 43, 2117 –2121
迄今最大的Mn84单分子磁体以及超分子纳米管
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![](https://wkrtcs.bdimg.com/rtcs/image?w=553&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"553","h":"471","dataType":"jpeg","c":"word/media/image4.jpeg","imgOriW":864,"imgOriH":736})
这是从文献中找到的一个晶体的分子结构图，虽然比较简单，但是比较漂亮。重要的是，它的结构清晰，行外人也可以理解看清！
它的中间部分是keggin结构的PMoV杂多酸，两边是2,2'-联吡啶合了Co的抗衡阳离子！
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![](https://wkrtcs.bdimg.com/rtcs/image?w=200&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"200","h":"137","dataType":"gif","c":"word/media/image5.gif"})
补充说明：第三大无机分子，分子中有176个钼，以及超过三倍的氧。
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![](https://wkrtcs.bdimg.com/rtcs/image?w=200&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"200","h":"170","dataType":"gif","c":"word/media/image6.gif"})
分子中60个W(灰)，8个P(红)，12个Ti(蓝)，全是最高价，全氧配位(多面体顶点)
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![](https://wkrtcs.bdimg.com/rtcs/image?w=550&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"550","h":"460","dataType":"jpeg","c":"word/media/image7.jpeg","imgOriW":1527,"imgOriH":1278})
![](https://wkrtcs.bdimg.com/rtcs/image?w=553&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"553","h":"356","dataType":"png","c":"word/media/image8.png","imgOriW":768,"imgOriH":494})
![](https://wkrtcs.bdimg.com/rtcs/image?w=553&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"553","h":"273","dataType":"jpeg","c":"word/media/image9.jpeg","imgOriW":877,"imgOriH":433})
由Cu和均苯三甲酸反应生成的一个金属有机骨架
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![](https://wkrtcs.bdimg.com/rtcs/image?w=300&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"300","h":"400","dataType":"jpeg","c":"word/media/image10.jpeg","imgOriW":300,"imgOriH":400})
![](https://wkrtcs.bdimg.com/rtcs/image?w=550&md5sum=d9034143dc30c16233e094286ec73c50&sign=7090aeca05&rtcs_flag=1&rtcs_ver=4&l=webapp&bucketNum=342&ipr={"t":"img","w":"550","h":"460","dataType":"jpeg","c":"word/media/image11.jpeg","imgOriW":846,"imgOriH":707})
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